What R-454B is and where it is used
R-454B is a blend of R-32 and the HFO R-1234yf, 68.9/31.1 by weight. Chemours sells it as Opteon XL41, Honeywell's PT chart lists it as Solstice 454B, and Carrier markets it as Puron Advance. Chemours positions it as a direct replacement for R-410A in new equipment only: window units, portables, ducted splits, mini-splits, multi-splits, PTACs, heat pumps and DX chillers. Its GWP is 465 (AR4, as listed by EPA), which Chemours puts at 78% below R-410A.
R-454B is ASHRAE safety group A2L: lower toxicity and lower flammability. Chemours notes that the latest UL 60335-2-40 equipment standard and ASHRAE 15, which covers field applications, have completed their evaluation of A2L refrigerants, and it says to check local regulations and standards such as UL, IEC or ASHRAE for the allowable system charge and safe handling requirements. Carrier says its Puron Advance products include a sensor that monitors for leaks and starts a fan to dissipate refrigerant if one is found. Follow the installation manual for charge limits and line sets, and read what A2L refrigerants change for techs before a first install.
How to read the R-454B chart
Chemours describes the glide of R-454B as very low, but it is a blend, so each temperature has two pressures. At 110 psig the dew point is 41.4°F and the bubble point is 39.0°F. Chemours' A/C guide uses the saturated vapor value for superheat and the saturated liquid value for subcooling.
- Superheat: convert suction pressure with the dew column. A 107 psig suction reading is 40.0°F. Subtract it from the suction line temperature.
- Subcooling: convert liquid line pressure with the bubble column. At 375 psig the bubble point is 116.0°F. Subtract the liquid line temperature from it.
Honeywell's Solstice 454B chart is laid out pressure-first: each gauge pressure lists an average, a bubble and a dew temperature. Chemours' Opteon XL41 data gives both a pressure-first and a temperature-first table. When charging a unit, follow the equipment manufacturer's chart or charging table.
The superheat calculator and subcooling calculator pick the right column. See bubble point, dew point and glide for why blends have two.
Example R-454B pressures on an air conditioner
The figures below are worked examples at assumed coil temperatures, not targets for any unit:
- Suction: at a 40°F evaporator dew point, R-454B reads about 107.0 psig, a little below R-410A at 118.4 psig.
- Head: at 115°F and 125°F condensing (bubble) temperatures, R-454B reads 370.1 psig and 422.3 psig. R-410A would read 392.3 psig and 448.0 psig.
At a 45°F evaporator and a 115°F condenser, Chemours rates R-454B at 97% of R-410A's capacity and 102% of its COP, with 82% of its mass flow. Charge to the method and values in the unit's installation manual, not to a pressure.
Service notes
- New equipment only: Chemours states that A2L refrigerants can only be used in new equipment and are not to be used as retrofit refrigerants, and that its Opteon XL refrigerants were developed for new equipment design only. Do not put R-454B in an R-410A system, and do not mix refrigerants.
- Charging: Chemours says to remove refrigerant blends from the cylinder as liquid. It also says the very low glide of R-454B means it can be topped off after leaks.
- Oil: Chemours lists R-454B as miscible with POE lubricant.
- Tools: for its Opteon XL refrigerants, Chemours lists 2L-certified recovery machines, leak detectors and gas detectors, recovery cylinders labeled flammable with left-hand threads, and a vacuum pump with its switch away from the work zone. It lists gauge manifolds, charging hoses and scales as routine, the same as for R-410A.
R-454B, R-410A and R-32
R-454B and R-32 are both A2L refrigerants that EPA lists under SNAP for new residential and light commercial AC and heat pumps, and both have GWPs under 700. At 40°F, R-410A dew reads 118.4 psig, R-454B dew reads 107.0 psig and R-32 reads 121.0 psig. Chemours says not to mix refrigerants, so charge only the refrigerant on the unit's nameplate. Compare them in R-410A vs R-454B and R-454B vs R-32.